AbstractTransiting planets like HD209458b offer a unique opportunity to scrutinize their atmospheric composition and structure. Transit spectroscopy probes the transition region between the day and night sides, called the limb. We present a re-analysis of existing HST/STIS transmission spectra of HD209458b's atmosphere. From these observations we identify H2 Rayleigh scattering, derive the absolute Sodium abundance and quantify its depletion in the upper atmosphere, extract a stratospheric T-P profile and find a temperature inversion and explain broad band absorptions with the presence of TiO and VO molecules.