The chemical composition of planets is determined by the distribution of the various molecular species in the protoplanetary disk at the time of their formation. To date, only a handful of disks have been imaged in multiple spectral lines with high spatial resolution. As part of a small campaign devoted to the chemical characterization of disk-outflow sources in Taurus, we report on new ALMA Band 6 (~1.3 mm) observations with ~0.15′′ (20 au) resolution toward the embedded young star DG Tau B. Images of the continuum emission reveals a dust disk with rings and, putatively, a leading spiral arm. The disk, as well as the prominent outflow cavities, are detected in CO, H₂CO, CS, and CN; instead, they remain undetected in SO₂, HDO, and CH₃OH. From the absorption of the back-side outflow, we inferred that the disk emission is optically thick in the inner 50 au. This morphology explains why no line emission is detected from this inner region and poses some limitations toward the calculation of the dust mass and the characterization of the inner gaseous disk. The H₂CO and CS emission from the inner 200 au is mostly from the disk, and their morphology is very similar. The CN emission significantly differs from the other two molecules as it is observed only beyond 150 au. This ring-like morphology is consistent with previous observations and the predictions of thermochemical disk models. Finally, we constrained the disk-integrated column density of all molecules. In particular, we found that the CH₃OH/H₂CO ratio must be smaller than ~2, making the methanol non-detection still consistent with the only such ratio available from the literature (1.27 in TW Hya).