Abstract We report a discovery of bright blob-like enhancements of an Fe i K$α$ line in the northwest and the middle of the supernova remnant (SNR) IC 443. The distribution of the line emission is associated with molecular clouds interacting with the shock front, and is totally different from that of the plasma. The Fe i K$α$ line has a large equivalent width. The most plausible scenario for the origin of the line emission is that the MeV protons accelerated in the shell leak into the molecular clouds and ionized the Fe atoms therein. The observed Fe i K$α$ line intensity is consistent with the prediction of a theoretical model in which MeV protons are accelerated along with GeV and TeV protons at the SNR.