ABSTRACT Here we present the discovery of 895 s-process-rich candidates from 454 180 giant stars observed by the Large Sky Area Multi-Object Fibre Spectroscopic Telescope (LAMOST) using a data-driven approach. This sample constitutes the largest number of s-process enhanced stars ever discovered. Our sample includes 187 s-process-rich candidates that are enhanced in both barium and strontium, 49 stars with significant barium enhancement only and 659 stars that show only a strontium enhancement. Most of the stars in our sample are in the range of effective temperature and log g typical of red giant branch (RGB) populations, which is consistent with our observational selection bias towards finding RGB stars. We estimate that only a small fraction (∼0.5 per cent) of binary configurations are favourable for s-process enriched stars. The majority of our s-process-rich candidates (95 per cent) show strong carbon enhancements, whereas only five candidates (<3 per cent) show evidence of sodium enhancement. Our kinematic analysis reveals that 97 per cent of our sample are disc stars, with the other 3 per cent showing velocities consistent with the Galactic halo. The scaleheight of the disc is estimated to be $z_{\rm h}=0.634 ± {0.063}\, \mathrm{kpc}$, comparable with values in the literature. A comparison with yields from asymptotic giant branch (AGB) models suggests that the main neutron source responsible for the Ba and Sr enhancements is the 13C(α,n)16O reaction. We conclude that s-process-rich candidates may have received their overabundances via mass transfer from a previous AGB companion with an initial mass in the range $1\!-\!3\, \mathrm{M}_{⊙ }$.