AbstractWe present a spectral decomposition technique that separates the contribution of different kinematic components in galaxies from the observed spectrum. This allows to study the kinematics and properties of the stellar populations of the individual components (e.g., bulge, disk, counter-rotating cores, orthogonal structures). Here, we discuss the results of this technique for galaxies that host counter-rotating stellar disks of comparable size. In all the studied cases, the counter-rotating stellar disk is the less massive, the youngest and has different chemical content (metallicity and α-elements abundance ratio) than the main galaxy disk. Further applications of the spectral decomposition technique are also discussed.